a vast range of surface coating materials all
producing their own combustion spectra
The following is a list of some of the more
common surface coating materials.
Tungsten carbide/cobalt
Chromium carbide/nickel chromium
Aluminium bronze
Copper nickel indium
Hard alloys of iron
To apply this technique of using
monochromatic ultra violet lighting and narrow band
pass filter to remove the combustion process,
theoretical research into the spectrum produced by
the specific process where autonomous control
would be beneficial is required. The reason for this
is that the emission spectra of flames is sensitive to
(Zirack):
temperature
gas/air or gas/oxygen mixture ratio
gas purity
burner type
gas flow (laminar or turbulent)
coating materials
height of observation in the flame
Research can however provide reasonable
indicators of a location for the band pass filter and
where spectral problems may arise. The thermal
spraying process used for this research was powder
thermal spraying using an Oxy-Acetylene torch.
4.2 Oxy-Acetylene Flame
The Oxy-Acetylene flame is a chemical reaction
resulting from the combination of acetylene C
2
H
2
with oxygen 0
2
. Figure 13 shows the two stages of
the chemical reactions (Materials Engineering
Group, MEG)
+
Figure 13: Oxy-Acetylene flame.
A neutral flame with products of combustion
CO
2
and H
2
O is produced with maximum heat
output when equal quantities of oxygen and
acetylene are used (MEG). Controlling this mixture
would form part of the overall thermal spraying
robot control system.
This is an idealised view and many other
ordinary molecules and unstable radicals are
produced in an Oxy-Acetylene flame in air.
4.3 Oxy-Acetylene Emission Spectra
The visible spectrum runs from 400 nm to 750 nm
and the infra red spectrum runs from 750 nm to 1
mm (HyperPhysics). This suggests a portion of the
ultra violet spectrum between 350 – 400 nm
commonly known as the UV-A spectrum for the
research as it excludes the visible and infra red
spectrum.
Research is now concentrated on identifying
weak spectra between 350 nm and 400 nm from the
powder flame spraying Oxy-Acetylene in air flame
with a range of molten surface coating materials,
which is widely used in the powder spraying
industry.
The ordinary molecules which are the stable
products of combustion, H
2
0
2
, C0
2
, C0, 0
2
or N
2
in
hydrogen flames do not provide spectra of any
appreciable strength in the visible or ultra violet
spectrum (Zirack).
The only product of combustion that may have
an appreciable spectrum in the UV band is the
hydroxyl radical OH which give band peaks at 281
nm 306 nm and 343 nm. Oxyacetylene flames not
only produce spectra of hydrogen flames but also
emit radiation of hydrocarbon radicals. Between the
350 nm and 400 nm wavelengths a weak CH band
occurs at 387/9 nm and a strong band at 432 nm are
found in air acetylene flames.
This suggests many wavelengths between 350
and 400 nm may be suitable for removing the Oxy-
Acetylene flame in air but we must add the spectrum
from the surface coating material to ensure there is
no appreciable interference from the molten material
in our chosen UV band. This is an area for continued
research. However a review of published work by
De Saro relating to emission spectra of molten
elements such as aluminium and copper provides
information on spectra of interest as follows:
Oxygen 0
2
Acetylene C
2
H
2
Stage 1
C
2
H
2
0
2
= 2C0 +H
2
Stage 2
C0 + H
2
+ 0
2
= C0
2
+ H
2
0
Aluminium 390 – 400 nm
Iron 260 – 262 nm
Magnesium 380 - 385 nm
Copper 320 – 330 nm
Results so far suggest using a narrow band pass
filter and lighting between 350 and 370 nm
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